Experimental spectrum from E. B. Mkadmi and H. Bürger
(Anorganische Chemie, Universität-Gesamthochschule, D-42097
Wuppertal, Germany).
References :
High-Resolution Fourier Transform Infrared Spectroscopy
and Analysis of the v3 Fundamental Band of P4,
V. Boudon, E. B. Mkadmi, H. Bürger and G. Pierre, Chemical
Physics Letters, 305, 21-27 (1999).
Rotational-Vibrational Relative Equilibria and the Structure of Quantum Energy Spectrum of the Tetrahedral Molecule P4, Ch. Van-Hecke, D. A. Sadovskií, B. I. Zhilinskií and V. Boudon, Journal of Molecular Spectroscopy, 17, 13-35 (2001).
Deuterated germane, GeD4
The ν1 band of GeD4
Experimental spectrum from R. Z. Martinez and D. Bermejo (Instituto de Estructura de la Materia, CSIC, Madrid, Spain).
Reference :
High Resolution Stimulated Raman Spectroscopy and Analysis of the v1 Stretching Bands of GeD4, V. Boudon, D. Radhouani, M. Loëte, R. Z. Martinez and D. Bermejo,Journal of Raman Spectroscopy, 38, 559-562 (2007).
Germanium Tetrafluoride, GeF4
Experimental spectrum from H. Bürger and E. B. Mkadmi (Anorganische Chemie, Universität-Gesamthochschule, D-42097 Wuppertal, Germany).
Reference :
High-Resolution Spectroscopy and Analysis of the v3 and v4 Fundamentals of Monoisotopic 70GeF4, V. Boudon, H. Bürger and E. B. Mkadmi, Journal of Molecular Spectroscopy, 206, 172-180 (2001).
Sulfur Hexafluoride, SF6
Experimental spectrum from M. Hepp and M. Herman (Lab.
Chimie Physique Moléculaire, ULB, CP 160/09, Av. Roosvelt
50, B-1050 Bruxelles, Belgium).
References :
High-Resolution Jet-Cooled Spectroscopy of SF6
: The v2+v6 Combination Band of 32SF6
and the v3 band of the rare isotopomers, V. Boudon,
M. Hepp, M. Herman, I. Pak and G. Pierre, Journal of Molecular
Spectroscopy, 192, 359-367 (1998).
Simultaneous Analysis of the v2 Raman and v2+v6
Infrared Spectra of the SF6 Molecule, D. Bermejo,
R. Z. Martínez, E. Loubignac, V. Boudon and G. Pierre,
Journal of Molecular Spectroscopy, 201, 164-171 (2000).
Experimental spectrum from H. Bürger (Anorganische
Chemie, Universität-Gesamthochschule, D-42097 Wuppertal,
Germany).
Reference :
High Resolution Spectroscopy and Analysis of the v4 Bending Region of SF6 Near 615 cm-1, V. Boudon, G. Pierre and H. Bürger,Journal of Molecular Spectroscopy, 205, 304-311 (2001).
The ν5 band of 34SF6
Experimental spectrum from J. L. Doménech, A. Ramos and D. Bermejo (Instituto de Estructura de la Materia, CSIC, Madrid, Spain).
Reference :
High Resolution Stimulated Raman Spectroscopy and Analysis of the v2, v5 and 2v4 Bands of 34SF6, V. Boudon, J. L. Doménech, A. Ramos, D. Bermejo and H. Willner,Molecular Physics, 16-17, 2653-2661 (2006).
Selenium Hexafluoride, SeF6
Experimental spectrum from H. Bürger (Anorganische Chemie, Universität-Gesamthochschule, D-42097 Wuppertal, Germany).
References :
Study of the v3=1 State of 80SeF6 by Fourier Transform Spectroscopy, M. Terki-Hassaine, G. Pierre, H. Bürger and H. Willner, Journal of Molecular Spectroscopy, 185, 93-97 (1997).
High-Resolution Spectroscopy and Analysis of the v4 band of 80SeF6, M. Rotger, V. Boudon, H. Bürger and H. Willner, Chemical Physics Letters, 339, 83-88 (2001).
Molybdenum Hexacarbonyl, Mo(CO)6
Experimental spectrum from P. Asselin, P. Soulard and
L. Manceron (Lab. Spectrochime Moléculaire, Univ.
P. et M. Curie, Cas courrier 49, Bât. F74, 4 Pl. Jussieu,
F-75252 Paris, France.).
Reference :
High-Resolution Fourier Transform Infrared Spectroscopy
and Analysis of the v6 Band of Jet-Cooled Mo(CO)6,
P. Asselin, P. Soulard, L. Manceron, V. Boudon and G. Pierre,
Journal of Molecular Structure (special issue honoring G. Graner),
517(1), 145-155 (2000).
The Rotational Energy
Surfaces for The v6 Band of Mo(CO)6.
Appearence of a diabolic point
(conical intersection) near J=7.
Click on the image above to view the movie (requires
QuickTime).
Reference :
Analysis of the "Unusual" Vibrational Components
of Triply Degenerate Vibrational Mode v6 of Mo(CO)6
Based on the Classical Interpretation of the Effective Rotation-Vibration
Hamiltonian, G Dhont, D. Sadovskiì, B. Zhilinskiì
and V. Boudon, Journal of Molecular Spectroscopy, 201,
95-108 (2000).
P4, GeD4, GeF4, SF6, SeF6, Mo(CO)6, and other examples ...
White Phosphorus, P4
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