Quelques exemples de spectres analysés

  • Imprimer

A FEW EXAMPLES OF SPHERICAL-TOP SPECTRA ANALYSES

 

Click on a molecule! hpoint right SF6OsO4, Adamantane, HMT, P4, GeD4, GeF4, SeF6, Mo(CO)6, and other examples ...

 

  • Sulfur Hexafluoride, SF6

SF6

 

SF6nu2p6

Experimental spectrum from M. Hepp and M. Herman (Lab. Chimie Physique Moléculaire, ULB, Brussels, Belgium).

References:

High-Resolution Jet-Cooled Spectroscopy of SF6 : The ν26 Combination Band of 32SF6 and the ν3 band of the rare isotopomers,
V. Boudon, M. Hepp, M. Herman, I. Pak and G. Pierre,
Journal of Molecular Spectroscopy, 192, 359-367 (1998).

Simultaneous Analysis of the ν2 Raman and ν26 Infrared Spectra of the SF6 Molecule,
D. Bermejo, R. Z. Martínez, E. Loubignac, V. Boudon and G. Pierre,
Journal of Molecular Spectroscopy, 201, 164-171 (2000).

 

 SF6nu4

Experimental spectrum from H. Bürger (Anorganische Chemie, Universität-Gesamthochschule, Wuppertal, Germany).

Reference:

High Resolution Spectroscopy and Analysis of the ν4 Bending Region of SF6 Near 615 cm-1,
V. Boudon, G. Pierre and H. Bürger,
Journal of Molecular Spectroscopy, 205, 304-311 (2001).

 

SF6nu5 34

Experimental spectrum from J. L. Doménech, A. Ramos and D. Bermejo (Instituto de Estructura de la Materia, CSIC, Madrid, Spain).

Reference:

High Resolution Stimulated Raman Spectroscopy and Analysis of the ν2, ν5 and 2ν4 Bands of 34SF6,
V. Boudon, J. L. Doménech, A. Ramos, D. Bermejo and H. Willner,
Molecular Physics, 104, 2653-2661 (2006).

 

Fig SF6 nu6

Experimental spectrum recorded at the AILES beamline of the SOLEIL Synchrotron (France).

Reference:

Resolving the forbidden band of SF6,
V. Boudon, L. Manceron, F. Kwabia Tchana, M. Loëte, L. Lago and P. Roy,
Physical Chemistry Chemical Physics, 16, 1415–1423 (2014).

 

  • Osmium Tetroxide, OsO4

OsO4

 

 Fig OsO4 nu3

Experimental spectrum recorded at the AILES beamline of the SOLEIL Synchrotron (France).

References:

High-Resolution Spectroscopy and Analysis of the ν13 Stretching Dyad of Osmium Tetroxide,
M. Louviot, V. Boudon, L. Manceron, P. Roy and D. Balcon,
Journal of Quantitative Spectroscopy and Radiative Transfer, 113, 119–127 (2012).

High-Resolution Spectroscopy and Structure of Osmium Tetroxide. A Benchmark Study on 192OsO4,
M. Louviot , V. Boudon, L. Manceron, D. Bermejo and R. Z. Martínez,
Inorganic Chemistry, 51, 10356–10365 (2012).

High-Resolution Stimulated Raman Spectroscopy and Analysis of the ν1 Band of OsO4,
M. Louviot , V. Boudon, D. Bermejo, R. Z. Martínez and L. Manceron,
Journal of Raman Spectroscopy, 44, 63–69 (2013).

 

  •  Adamantane, C10H16

C10H16

 

Fig HMT nu22

Experimental spectrum recorded at the AILES beamline of the SOLEIL Synchrotron (France).

Reference:

Rotationally resolved IR spectroscopy of adamantane.
O. Pirali, V. Boudon, J. Oomens and M. Vervloet,
The Journal of Chemical Physics, 136, 02431-1–024310-12 (2012)

 

  • Hexamethylenetetramine (HMT), C6N4H12

C6N4H10

 

Fig HMT nu22

Experimental spectrum recorded at the AILES beamline of the SOLEIL Synchrotron (France).

Reference:

Rotationally resolved IR spectroscopy of hexamethylenetetramine (HMT) C6N4H12.
O. Pirali, V. Boudon, N. Carrasco, and E. Dartois,
Astronomy and Astrophysics, 561, A109 (2014)

 

  • White Phosphorus, P4

P4

 

P4nu3

Experimental spectrum from E. B. Mkadmi and H. Bürger (Anorganische Chemie, Universität-Gesamthochschule, Wuppertal, Germany).

References:


High-Resolution Fourier Transform Infrared Spectroscopy and Analysis of the ν3 Fundamental Band of P4,
V. Boudon, E. B. Mkadmi, H. Bürger and G. Pierre,
Chemical Physics Letters, 305, 21-27 (1999).

Rotational-Vibrational Relative Equilibria and the Structure of Quantum Energy Spectrum of the Tetrahedral Molecule P4,
Ch. Van-Hecke, D. A. Sadovskií, B. I. Zhilinskií and V. Boudon,
European Physical Journal D, 17, 13-35 (2001).

 

  • Deuterated Germane, GeD4

GeH4

 

GeD4nu1

Experimental spectrum from R. Z. Martinez and D. Bermejo (Instituto de Estructura de la Materia, CSIC, Madrid, Spain).

Reference:

High Resolution Stimulated Raman Spectroscopy and Analysis of the ν1 Stretching Bands of GeD4,
V. Boudon, D. Radhouani, M. Loëte, R. Z. Martinez and D. Bermejo,
Journal of Raman Spectroscopy, 38, 559-562 (2007).

 

  • Germanium Tetrafluoride, GeF4

 GeF4

 

GeF4n3n4

Experimental spectrum from H. Bürger and E. B. Mkadmi (Anorganische Chemie, Universität-Gesamthochschule, Wuppertal, Germany).

Reference:

High-Resolution Spectroscopy and Analysis of the ν3 and ν4 Fundamentals of Monoisotopic 70GeF4,
V. Boudon, H. Bürger and E. B. Mkadmi,
Journal of Molecular Spectroscopy, 206, 172-180 (2001).

 

  • Selenium Hexafluoride, SeF6

SeF6

 

SeF6nu4

Experimental spectrum from H. Bürger (Anorganische Chemie, Universität-Gesamthochschule, Wuppertal, Germany).

References:

Study of the v3=1 State of 80SeF6 by Fourier Transform Spectroscopy,
M. Terki-Hassaine, G. Pierre, H. Bürger and H. Willner,
Journal of Molecular Spectroscopy, 185, 93-97 (1997).

High-Resolution Spectroscopy and Analysis of the ν4 band of 80SeF6,
M. Rotger, V. Boudon, H. Bürger and H. Willner,
Chemical Physics Letters, 339, 83-88 (2001).

 

  • Molybdenum Hexacarbonyl, Mo(CO)6

MoCO6

 

MoCO6nu6

Experimental spectrum from P. Asselin, P. Soulard and L. Manceron (MONARIS, Paris, France).

References:

High-Resolution Fourier Transform Infrared Spectroscopy and Analysis of the ν6 Band of Jet-Cooled Mo(CO)6,
P. Asselin, P. Soulard, L. Manceron, V. Boudon and G. Pierre,
Journal of Molecular Structure, 517, 145-155 (2000).

Analysis of the "Unusual" Vibrational Components of Triply Degenerate Vibrational Mode ν6 of Mo(CO)6 Based on the Classical Interpretation of the Effective Rotation-Vibration Hamiltonian,
G Dhont, D. Sadovskiì, B. Zhilinskiì and V. Boudon,
Journal of Molecular Spectroscopy, 201, 95-108 (2000).

 

  • See also in the same field

- Spectroscopy of methane
- Spectroscopy of open-shell (colored) hexafluorides
- TDS spectroscopy software
- Spherical tops